Feature Requestush Great news! This feature is available

Wix Bookings Request: Setting Specific Time Slots for Appointments

Currently, it is not possible to set specific time slots for appointments. For example, it is not possible to set working hours for every other Saturday or to set a different schedule every week. 
However, you can create a class service and set the maximum number of participants to 1. You can then manually add the participant(s) to each class session, as required. 
Tip:
You can change your business hours at any time.
We are always working to update and improve our products, and your feedback is hugely appreciated.
If this is a feature you would like to see in the future, please click Vote for this feature and we'll make sure to keep you updated.